Among all the odd-shaped mountains that adorn the Rio horizon, Sugarloaf (Pão de Açúcar in Portuguese) stands apart for its majesty and fortuitous placement. Sugarloaf is part of a single landmark along with sister peak Urca, to which it connects via a now-century-old cable car locals call the bondinho. When you reach the top of the rounded outcropping, 1,300 feet up, it’s hard to decide what to look at: You’ve got 360 degrees of Rio from on high. The recommended (and most sought-after) visiting hour is sunset. Yet there’s no hurry to descend before night falls. Seeing the lights come up in the cidade maravilhosa is well worth a tarry.